Report WG1
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چکیده
1) Formation of an oxazolidin-5-one intermediate, subsequent decarboxylation under relatively mild conditions to a stable azomethine ylide, rearrangement to the corresponding Amadori product and final beta β-elimination to afford AA. This pathway can be considered marginal (1-5%) versus the classical Amadori route. In this case, the rate limiting step is the β-elimination reaction. Other groups have also shown the general applicability of the β-elimination pathway to other amino acids shown (e.g. phenylalanine to styrene, aspartic acid to acrylic acid, etc.).
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تاریخ انتشار 2004